Fertilizer

Phosphorous (P2O5)
To extract phosphoric acid from such elements as monazite and xenotime you would use a process known as the wet-process phosphoric acid. To extract phosphorous the temperature needs to be substantially high in order for the phosphoric acid to polymerize. It becomes superphosphoric acid when the phosphoric acid begins to lose more and more water.

phosphoric acid formed:

3Ca3(PO4)2 x CaF2 + 10H2SO4 + 20H2O -->

6H3PO4 + 10CASO4 x 2H2O + 2HF

extracting phosphorous reaction:

2Ca3(PO4)2(s) + 6SiO2(s) --> 6CaSiO3(l) + 10CO(g) + P4 (g)

To contain and store superphosphoric acid, a more “pure” and concentrated form of phosphorous, you need to keep it in a high temperature environment. Ammonia reacts with monocalcium phosphate to form the reaction formula:

Ca(H2PO4)2 x H2O + NH3 --> CaHPO4 + NH4H2PO4 + H2O

The curing process allows complete reaction of the sulfuric acid by penetration of the phosphate rock which maximizes the availability of the P O content. To extract phosphorous from orthophosphoric acid, H PO , we use either of the two processes: the electric furnace or acidulation of phosphate rock.

Work Cited

Bat City: http://www/synaptic.bc.ca/ejournal/batcity2.htm

“Bat Guano” : http://www.naturagro.com/description.html

 

 

 

 

 

“Beans and fungus may… fertilizer” : http://www.globaltechnoscan.com/15thAug-21Aug02/corn_crop.htm

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“Fertilizer Compounds”: http://www.hydro-gardens.com/fertcomp.htm

Illinois Fertilizer Conference Proceedings: Managing Phosphorus: Agronomic and Environmental Concerns <http://frec.cropsci.uiuc.edu/1999/report1/>

The Macdonald Encyclopedia of: Rocks and Minerals Macdonald & Co. 1983 London & Sydney

"Mineral." Britannica Student Encyclopedia. 2003. Encyclopaedia Britannica Online. 01 May, 2003 <http://search.eb.com/ebi/article?eu=297862>.

McGraw-Hill Dictionary of Scientific and Technical Terms sixh edition 2003 New York

McGraw-Hill “Encyclopedia of science & technology” 8th ed.1997 Library of Congress Cataloging (p. 81-95)

Richard J. Lewis, Sr. Condensed Chemical Dictionary twelfth edition 1993 Van Nostrand Reinhold Company New York

 

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