The Chemistry of Soap

The non- polar hydrocarbon end of the soap molecule is repelled by water. Here is a diagram of the monolayer of soap, which is made by a drop or two of soap in water, when the soap molecules "stand up"(because the non polar hydrocarbon tails are repelled by water), on the surface as the polar carboxyl salt end is attracted to the polar water.

Figure 5: Monolayer of Soap on Water

Vocabulary List

Saponification: The process of soap making
Basic hydrolysis reaction: The process of soap making
Brine: leftover of saponification
Salt: the result of an acid and an alkali reacting together.
Lye: sodium hydroxide
Potash: potassium hydroxide
triglyceride molecule: they are made up of three fatty acid molecules that are attached to one molecule of glycerine. There are many types of triglycerides that each consists of it’s own particular combination of fatty acids.
fatty acids: long chain of hydrogen and carbon that contains an extra hydrogen atom at one end and a carboxyl group at the other, which is basically made up of two oxygen and one hydrogen and carbon atom.
Alkali: The base, either sodium hydroxide or potassium hydroxide, depending on which is used.
Hard Soap: produced by long-chain fatty acids that don’t mix well with water
Soft Soap: produced by shorter hydrocarbon chains into semi- solid and liquid soaps.
Glycerin: A byproduct of making soap out of natural ingredients when fats or oils are reacted with alkali.

 

 

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