| Iron Metallurgy (continued) |
by
Alex Cecil
|
|
Generally,
you don't have to make iron in the laboratory because it's available commercially.
But, because iron will only be found in its raw form on Arda, our
group must figure out how to purify the iron the colonists will find lying
around. Small amounts of pure iron can be made
through the purification of crude iron with carbon monoxide. The intermediate
in this process is iron pentacarbonyl, Fe(CO)5. The carbonyl
decomposes on heating to about 250°C to form pure iron powder.
The
Fe(CO)5 is a volatile oily complex which is easily flushed
from the reaction vessel leaving the impurities behind.
This method is one the colonists might use (obtaining the CO by
burning charcoal and trapping the byproduct) to purify the iron. Another method is the reduction of iron oxide, Fe2O3,
with hyrogen, H2. Also,
nearly all iron produced commercially is made with a blast furnace. Assuming
that the colonists can create a blast furnace, here is the reaction that
takes place. Iron oxide, Fe2O3, is reduced with
carbon (as coke) although in the furnace the actual reducing agent is
probably carbon monoxide, CO.
Finally,
according to WebElements.com, "This process is one of the most significant
industrial processes in history and the origins of the modern process
are traceable back to a small town called Coalbrookdale in Shropshire
(England) around the year 1773." |
Iron
metallurgy.
Images fig.1 <east_west_dialogue.tripod.com/ dialogue/id1.html> figs
2&3: Iron metallurgy. fig.4 <http://www.meconlimited.com/ steel1.htm> fig.5 <http://www.shef.ac.uk/uni/academic/D-H/em/short_courses/ferrous.html |